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--- chrysopogon_zizanioides_l._roberty [2021/03/12 07:20] – andreas
+++ chrysopogon_zizanioides_l._roberty [2021/05/27 07:47] (aktuell) – andreas
@@ Zeile 54: / Zeile 54: @@
 "The manufacture of vetiveryl acetate modulates the initial scent of vetiver essential oil by suppressing the notes brought by the main fragrant alcohols. While the impact of undesired odorant molecules such as phenol derivatives and geosmin is lowered, the major odour-active ketones such as khusimone, ziza-6(13)-en-3-ones, and the two vetivones develop their own odor characters in vetiveryl acetate." \\
+Main components of vetiveryl acetate preparations were β-vetivenene (~0-1%), ylangen-15-yl acetate (~0-1%), cyclocopacamphan-12-yl acetate A (~1-3%), cyclocopacamphan-12-yl acetate B (~1-3%), khusian-2-yl acetate (~1-2%), ziza-6(13)en-3α-yl acetate (~1-2%), β-funebren-14-yl acetate (~1-2%), β-vetivone (~2-3%), ziza-6(13)en-3β-yl acetate (~1-2%), isokhusimyl acetate (~0-2%), vetiselinenyl acetate (~3-10%), α-vetivone (~1-4%), khusimyl acetate (~11-27%), α-isonootkatyl acetate (~1-7%), and (E)-isovalencenyl acetate (~3-28%). \\
 [Tissandié, Loïc, et al. "Integrated comprehensive two-dimensional gas-chromatographic and spectroscopic characterization of vetiveryl acetates: Molecular identifications, quantification of constituents, regulatory and olfactory considerations." Journal of Chromatography A 1573 (2018): 125-150]
 The citrusy grapefruit character of vetiver oil originates from α-vetivone, β-vetivone, and nootkatone, earthy aspects are due to geosmine and nor-acorenone, and the creamy santal character mainly results from (E)-isovalencenol. The typical transparent woody-ambery character of vetiver is contributed by ziza-6(13)en-3-one (th 0.13 ng/L air) and 2-epi-ziza-6(13)en-3-one (th 0.029 ng/L air), now proved by synthesis of all (1R)-configured ziza-6(13)-en-3-one stereoisomers. \\
-[List, Benjamin, et al. "The Odorous Principle of Vetiver Oil, Unveiled by Chemical Synthesis." Angew. Chem. Int. Ed.2021, 60, 1-7] \\
+[Ouyang, Jie, et al. "The Smelling Principle of Vetiver Oil, Unveiled by Chemical Synthesis." Angewandte Chemie (International Ed. in English) 60.11 (2021): 5666] \\
-[[https://onlinelibrary.wiley.com/doi/epdf/10.1002/anie.202014609]]
+[[https://www.ncbi.nlm.nih.gov/pmc/articles/PMC7986879/]]
-{{chrysopogon_zizanoides.jpg?800}} \\
+{{chrysopogon_zizanoides.jpg}} \\
 Chrysopogon zizanioides-seeding habit-Kokomo Haiku (2009) \\
  [[https://commons.wikimedia.org/wiki/File:Chrysopogon_zizanioides-seeding_habit-Kokomo_Haiku.jpg|Wikimedia Commons]], Author: Forest and Kim Starr  [[https://creativecommons.org/licenses/by/2.0/deed.en|CC BY-SA 2.0]]